Phase equilibria and thermodynamics of the Bi-Sb-Sn ternary system

被引：26
|
作者：
Manasijevic, Dragan
Vrest'al, Jan
Minic, Dusko
Kroupa, Ales
Zivkovic, Dragana
Zivkovic, Ivan
机构：
[1] Univ Belgrade, Tech Fac, Bor 19210, Serbia
[2] Masaryk Univ, Fac Sci, Inst Theoret & Phys Chem, Brno 61137, Czech Republic
[3] Univ Pristina, Min & Met Fac, Kosovska Mitrovica 38220, Serbia
[4] Acad Sci Czech Republ, Inst Phys Mat, Brno 61662, Czech Republic
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2007年 / 438卷 / 1-2期
关键词：
Bi-Sb-Sn system; phase diagram; thermodynamics;
D O I：
10.1016/j.jallcom.2006.08.021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Phase equilibria in the Bi-Sb-Sn ternary system have been studied experimentally as well as by using the calculation of phase diagram (CALPHAD) method. New experimental SEM-EDX and DTA results were used together with the literature data in this thermodynamic assessment. Solubility of bismuth in SbSn phase and ternary corrections for Liquid and Rhombo-A7 phase were established. Calculated values of thermodynamic functions were collated with recently published experimental thermodynamic results for liquid phase at 900 K. Calculated isothermal sections at 200 degrees C and 300 degrees C were compared with our own experimental results based on the SEM-EDX analysis of composition of phases. Three calculated vertical sections were successfully compared with the DTA results from this work and from literature data. Reasonable agreement between calculation and experimental data was observed in all cases. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：150 / 157
页数：8
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