Solid electrolyte type ammonia gas sensor based on trivalent aluminum ion conducting solids

被引：39
|
作者：
Nagai, Tsukasa [1 ,2 ]
Tamura, Shinji [1 ]
Imanaka, Nobuhito [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] Japan Soc Promot Sci, Chiyoda Ku, Tokyo 1028472, Japan
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2010年 / 147卷 / 02期
基金：
日本学术振兴会;
关键词：
Solid electrolyte; Ammonia gas sensor; Rare-earth sulfate; Ammonium hydrogen phosphate; Rare-earth oxysulfate; AUXILIARY SENSING ELECTRODE; AL3+; TEMPERATURE; FILMS; NH3;
D O I：
10.1016/j.snb.2010.03.093
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Ammonia gas sensors were fabricated by using trivalent aluminum ion conducting (Al0.2Zr0.8)(20/19)Nb(PO4)(3) solid electrolyte with aluminum metal film as a reference electrode. As the auxiliary sensing electrode material, praseodymium ammonium double sulfate Pr-2(SO4)(3).(NH4)(2)SO4 or (NH4)(2)HPO4 doped La2O2SO4 solid solution, 0.7La(2)O(2)SO(4)-0.3(NH4)(2)HPO4, was applied from the view points of thermal stability or water durability. The former sensor with Pr2(SO4)3.(NH4)2SO4 showed a rapid response and the latter one with 0.7La(2)O(2)SO(4)-0.3(NH4)(2)HPO4 exhibited a theoretical response even in a humid atmosphere. Since the present sensors applying Al3+ ion conductor showed such a high sensing performance of rapid response or high durability for water, it is greatly expected to be practical NH3 gas sensors. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：735 / 740
页数：6
相关论文
共 50 条
  • [1] New type of sulfur dioxide gas sensor based on trivalent Al3+ ion conducting solid electrolyte
    Inaba, Yuichi
    Tamura, Shinji
    Imanaka, Nobuhito
    [J]. SOLID STATE IONICS, 2008, 179 (27-32) : 1625 - 1627
  • [2] New type of trivalent gadolinium ion conducting solid electrolyte
    Tamura, S.
    Yamamoto, S.
    Imanaka, N.
    [J]. JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, 2008, 11 (01) : 1 - 4
  • [3] Low Temperature Operable CO2 Gas Sensor Based on Trivalent Aluminum Ion Conducting Solid
    Nagai, Tsukasa
    Tamura, Shinji
    Imanaka, Nobuhito
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2011, 14 (12) : J81 - J83
  • [4] New trivalent ion conducting solid electrolyte with the NASICON type structure
    Hasegawa, Y
    Tamura, S
    Imanaka, N
    Adachi, G
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 379 (1-2) : 262 - 265
  • [5] Development of Ammonia Gas Sensors Based on Trivalent Al3+ Cation Conducting Solid Electrolyte
    Nagai, Tsukasa
    Tamura, Shinji
    Imanaka, Nobuhito
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2012, 85 (05) : 634 - 641
  • [6] Trivalent praseodymium ion conducting solid electrolyte composite with NASICON type structure
    Hasegawa, Y
    Tamura, S
    Imanaka, N
    Adachi, G
    Takano, Y
    Tsubaki, T
    Sekizawa, K
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 375 (1-2) : 212 - 216
  • [7] Solid electrolyte-type gas sensors applied trivalent cation conducting solid electrolytes
    Tamura, Shinji
    Imanaka, Nobuhito
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2022, 368
  • [8] A hydrogen sensor based on a hydrogen ion conducting solid electrolyte
    Maffei, N
    Kuriakose, AK
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1999, 56 (03) : 243 - 246
  • [9] Nitrogen oxides gas sensor based on Al3+ ion conducting solid electrolyte
    Tamura, Shinji
    Hasegawa, Isao
    Imanaka, Nobuhito
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2008, 130 (01) : 46 - 51
  • [10] Solid Electrolyte Type Ammonia Gas Sensor with High Water Durability
    Tamura, S.
    Nagai, T.
    Imanaka, N.
    [J]. CHEMICAL SENSORS 10 -AND- MEMS/NEMS 10, 2012, 50 (12): : 189 - 194
12345