An unprecedented intramolecular coupling of o-carboranyl and cyclopentadienyl.: Synthesis and structural characterization of a ruthenium complex containing a novel doubly-bridged cyclopentadienylcarboranyl ligand

被引：19

作者：

Sun, Y

Chan, HS

Dixneuf, PH

Xie, ZW ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[2] Univ Rennes 1, CNRS, UMR Organomet & Catalyse 6509, Inst Chim Rennes, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 22期

关键词：

D O I：

10.1039/b409772f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel ruthenium-mediated coupling reaction of a carboranyl with a cyclopentadienyl was discovered for the first time, leading to a brand new doubly-bridged cyclopentadienyl-carboranyl ligand bearing two five-membered rings and to a new type of chiral ruthenium complex.

引用

页码：2588 / 2589

页数：2

相关论文

共 3 条

[1] Reaction scope and mechanism of sterically induced ruthenium-mediated intramolecular coupling of o-carboranyl with cyclopentadienyl.: Synthesis and structure of ruthenium complexes incorporating doubly linked cyclopentadienyl-carboranyl Ligands
Sun, Yi
Chan, Hoi-Shan
Xie, Zuowei
[J]. ORGANOMETALLICS, 2006, 25 (17) : 4188 - 4195
[2] Oxidative coupling of an anionic gallium(I) carbene analogue:: Synthesis and structural characterization of an unprecedented π-cyclopentadienyl-bridged digallane complex
Baker, RJ
Jones, C
Kloth, M
Platts, JA
[J]. ORGANOMETALLICS, 2004, 23 (21) : 4811 - 4813
[3] SYNTHESIS AND CHEMICAL CHARACTERIZATION OF COMPLEXES CONTAINING SEMIQUINONE UNITS BRIDGED BY PENTAOXODIMOLYBDATE GROUPS - STRUCTURAL AND ELECTROCHEMICAL STUDIES OF [(N-C4H9)4N]2[MO4O10(C6H2O4)2] AND [(N-C4H9)4N]3[MO6O15(C6O6)2] AND OF AN ANALOGOUS TETRAOXYDIBENZOFURAN COMPLEX, [(N-C4H9)4N]2[MO4O10(C12H4O5)2], PREPARED FROM METAL-MEDIATED RADICAL COUPLING OF 1,2,4-TRIHYDROXYBENZENE PRECURSORS6
LIU, SC
SHAIKH, SN
ZUBIETA, J
[J]. INORGANIC CHEMISTRY, 1989, 28 (04) : 723 - 732

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