Synthesis of well-defined allyl end-functionalized polystyrene by atom transfer radical polymerization with an allyl halide initiator

被引：61
|
作者：
Nakagawa, Y [1 ]
Matyjaszewski, K [1 ]
机构：
[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
来源：
POLYMER JOURNAL | 1998年 / 30卷 / 02期
关键词：
allyl; atom transfer radical polymerization; azide; end functional polymers; living radical polymerization; polystyrene;
D O I：
10.1295/polymj.30.138
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The allyl chloride and allyl bromide initiated atom transfer radical polymerization, ATRP, of styrene was conducted to afford alpha-allyl-omega-halopolystrene with molecular weights predetermined by Delta[M]/[I](0) and with low polydisperities M-w/M-n approximate to 1.2 for allyl bromide and M-w/M-n approximate to 1.3 for allyl chloride. The structure of the alpha-allyl-omega-halopolystyrene was confirmed by H-1 NMR spectra. The halogen end-groups were transformed to azido group quantitatively with trimethylsilyl azide in the presence of tetrabutylammonium fluoride.
引用
收藏
页码：138 / 141
页数：4
相关论文
共 50 条
  • [1] Synthesis of Well-Defined Allyl End-Functionalized Polystyrene by Atom Transfer Radical Polymerization with an Allyl Halide Initiator
    Yoshiki Nakagawa
    Krzysztof Matyjaszewski
    [J]. Polymer Journal, 1998, 30 : 138 - 141
  • [2] Synthesis of well-defined azido and amino end-functionalized polystyrene by atom transfer radical polymerization
    Matyjaszewski, K
    Nakagawa, Y
    Gaynor, SG
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 1997, 18 (12) : 1057 - 1066
  • [3] Synthesis and coordination of oxyquinolyl end-functionalized polystyrene by atom transfer radical polymerization
    Guo, X
    Lu, JM
    Li, H
    Yao, SH
    Wang, LH
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 97 (05) : 2067 - 2071
  • [4] Atom transfer radical polymerization of styrene using a novel octafunctional initiator: Synthesis of well-defined polystyrene stars
    Angot, S
    Murthy, KS
    Taton, D
    Gnanou, Y
    [J]. MACROMOLECULES, 1998, 31 (21) : 7218 - 7225
  • [5] Synthesis of well-defined polystyrene macrophotoinitiators by atom-transfer radical polymerization
    Degirmenci, M
    Cianga, I
    Yagci, Y
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2002, 203 (10-11) : 1279 - 1284
  • [6] Well-defined dibenzocyclooctyne end functionalized polymers from atom transfer radical polymerization
    Yang, Xiaoke
    Wang, Shuangshuang
    Yan, Yechao
    Wu, Ying
    Zhang, Ke
    Chen, Yongming
    [J]. POLYMER, 2014, 55 (05) : 1128 - 1135
  • [7] Synthesis of well-defined polyacrylonitrile by atom transfer radical polymerization
    Matyjaszewski, K
    Jo, SM
    Paik, HJ
    Gaynor, SG
    [J]. MACROMOLECULES, 1997, 30 (20) : 6398 - 6400
  • [8] Synthesis of a well-defined glycopolymer by atom transfer radical polymerization
    Ohno, K
    Tsujii, Y
    Fukuda, T
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1998, 36 (14) : 2473 - 2481
  • [9] Synthesis of a well-defined anthracene-labelled polystyrene by atom-transfer radical polymerization
    Ohno, K
    Fujimoto, K
    Tsujii, Y
    Fukuda, T
    [J]. POLYMER, 1999, 40 (03) : 759 - 763
  • [10] Synthesis of a well-defined naphthalene-labeled polystyrene via atom transfer radical polymerization
    Cheng, ZP
    Zhu, XL
    Zhu, J
    Lu, JM
    Yu, JH
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2005, A42 (03): : 341 - 349
12345