Transitions of calcium carbonate crystals controlled by self-assembly supermolecule of β-cyclodextrin and sodium dodecyl benzene sulfonate

被引:16
|
作者
Nan, Zhaodong [1 ]
Chen, Xiangna [2 ]
Yang, Qianqian [1 ]
Chen, Zhiying [1 ]
机构
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
[2] Qufu Normal Univ, Coll Chem Sci, Qufu 273165, Peoples R China
关键词
Inorganic compound; Crystal growth; X-ray diffraction; INCLUSION COMPLEX; VATERITE; ARAGONITE; SULFATE; CRYSTALLIZATION; PRECIPITATION; AGGREGATION; SURFACTANT; PARTICLES; CACO3;
D O I
10.1016/j.materresbull.2010.02.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The transitions from vaterite to calcite and (tom vaterite to aragonite, were found with the anionic surfactant sodium dodecyl benzene sulfonate and beta-cyclodextrin as a template, respectively. when the experimental temperature was controlled at 90 degrees C The transition from calcite to aragonite was found when the experimental temperature was controlled at 120 degrees C The molar ratio of 1.1 and 1 2 supermolecules composed of sodium dodecyl benzene sulfonate on and beta-cyclodextrin molecule may be formed at 90 and 120 degrees C, respectively The possible formation mechanisms of different CaCO(3) polymorphs are proposed based on the "structural correspondence" (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:722 / 726
页数:5
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