Study of cephalexin and cefaclor adsorption at the mercury/solution interface by AC polarography

被引:16
|
作者
Erceg, M
Kapetanovic, V
Suznjevic, D
Dumanovic, D
机构
[1] UNIV BELGRADE,DEPT ANALYT CHEM,FAC PHARM,BELGRADE,YUGOSLAVIA
[2] KRALJICE ANE BB,FORENS INST,BELGRADE,YUGOSLAVIA
[3] INST GEN & PHYS CHEM,BELGRADE,YUGOSLAVIA
[4] ICN,GALENIKA INST,BELGRADE,YUGOSLAVIA
关键词
D O I
10.1006/mchj.1997.1493
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The adsorptive properties of Cephalexin (Cef), Cefaclor (Cfx), and 7-aminodesacetoxycephalosporanic acid (7-ADCA) were examined by applying phase sensitive ac polarography with DME in order to compare the behavior of their molecules at a mercury electrode. To find optimal conditions for the distinct adsorption effects and to determine the ionic species participating in adsorption, the influence of pH and concentration (concerning electrical double layer characteristics at the mercury/solution interface) was studied. (C) 1997 Academic Press.
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页码:73 / 80
页数:8
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