Metal Nickel Foam as an Efficient and Stable Electrode for Hydrogen Evolution Reaction in Acidic Electrolyte under Reasonable Overpotentials

被引：129

作者：

Lu, Jia ^{[1
]}

Xiong, Tanli ^{[1
]}

Zhou, Weijia ^{[1
]}

Yang, Linjing ^{[1
]}

Tang, Zhenghua ^{[1
]}

Chen, Shaowei ^{[1
,2
]}

机构：

[1] S China Univ Technol, New Energy Res Inst, Sch Environm & Energy, Guangzhou Higher Educ Mega Ctr, Guangzhou 510006, Guangdong, Peoples R China

[2] Univ Calif Santa Cruz, Dept Chem & Biochem, 1156 High St, Santa Cruz, CA 95064 USA

来源：

ACS APPLIED MATERIALS & INTERFACES | 2016年 / 8卷 / 08期

基金：

中国国家自然科学基金;

关键词：

stable electrocatalyst; equilibrium potential; hydrogen evolution reaction; nickel foam; acidic electrolyte; ELECTROCATALYST; NANOPARTICLES; NANOSHEETS; FRAMEWORKS; CATALYSIS; PHOSPHIDE; SURFACE;

D O I：

10.1021/acsami.6b00233

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Acidic electrolytes are advantageous for water electrolysis in the production of hydrogen as there is a large supply of H+ ions in the solution. In this study, with the applied overpotential larger than the equilibrium potential of Ni-0/Ni2+, Ni foam as HER electrode exhibits excellent and stable HER activity with an onset potential of -84 mV (vs RHE), a high current density of 10 mA cm(-2) at -210 mV (vs RHE), and prominent electrochemical durability (longer than 5 days) in acidic electrolyte. The results presented herein may has potential large-scale application in hydrogen energy production.

引用

页码：5065 / 5069

页数：5

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