Controlled radical copolymerization of styrene and maleic anhydride and the synthesis of novel polyolefin-based block copolymers by reversible addition-fragmentation chain-transfer (RAFT) polymerization

被引：0

作者：

De Brouwer, H ^{[1
]}

Schellekens, MAJ ^{[1
]}

Klumperman, B ^{[1
]}

Monteiro, MJ ^{[1
]}

German, AL ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Dept Polymer Chem, NL-5600 MB Eindhoven, Netherlands

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2000年 / 38卷 / 19期

关键词：

controlled radical polymerization; RAFT; block copolymers; polyolefin; styrene; maleic anhydride; addition-fragmentation; degenerative transfer;

D O I：

10.1002/1099-0518(20001001)38:19<3596::AID-POLA150>3.0.CO;2-F

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Reversible addition-fragmentation chain transfer (RAFT) was applied to the copolymerization of styrene and maleic anhydride. The product had a low polydispersity and a predetermined molar mass. Novel, well-defined polyolefin-based block copolymers were prepared with a macromolecular RAFT agent prepared from a commercially available polyolefin (Kraton L-1203). The second block consisted of either polystyrene or poly(styrene-co-maleic anhydride). Furthermore, the colored, labile di-thioester moiety in the product of the RAFT polymerizations could be removed from the polymer chain by UV irradiation. (C) 2000 John Wiley & Sons, Inc.

引用

页码：3596 / 3603

页数：8

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