A one-step synthesis of protected functionalised titanocene dichlorides

被引：34
|
作者：
McGowan, MAD [1 ]
McGowan, PC [1 ]
机构：
[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 07期
关键词：
anti-tumour agents; cyclopentadienyl; functionalisd titanocene dichlorides; one step synthesis; water soluble titanium (IV) complexes;
D O I：
10.1016/S1387-7003(00)00094-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report a novel, high yield one-step synthesis of water stable and soluble titanocene dichloride dihydrochloride salts from the direct reaction of the neutral amino-substituted cyclopentadienes with TiCl4. The following novel complexes have been synthesised: C5H4(CH2)(2)N(CH (2))(5)](2)TiCl2 (5), [C5H4CH(CH (2))(4)NMe](2)TiCl2, (6), [C5H4(CH (2))(2)N(CH (2))(5)](2)TiCl2 . 2HCl (7), [C5H4CH(CH2)(4)](2)NMeTiCl2 . 2HCl (8), [C5H4(CH2)(2)N(CH2)(5)](2)TiMe2 (9). (C) 2000 Elsevier Science S.A. All rights reserved.
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页码：337 / 340
页数：4
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