Syntheses, topological networks and properties of four complexes based on 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand

被引：16
|
作者：
He, Xiang [1 ]
Liu, Jing-Jing [1 ]
Guo, Hong-Mei [1 ]
Shao, Min [2 ]
Li, Ming-Xing [1 ]
机构：
[1] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Instrumental Anal & Res Ctr, Shanghai 200444, Peoples R China
来源：
POLYHEDRON | 2010年 / 29卷 / 03期
关键词：
4-Amino-3,5-bis(3-pyridyl)-1,2,4-triazole; Coordination polymer; Crystal structure; Thermal analysis; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; SYSTEM; MOTIFS; CHAINS; NETS;
D O I：
10.1016/j.poly.2009.11.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of metal acetates with 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole (3-abpt) and co-ligands gave rise to four new complexes, namely [Zn-2(3-abpt)(beta)(DMF) (H2O)(2)](n) nH(2)O (1), [Zn(3-abpt)(1p)](n) 3nH(2)O (2), [Zn(3-abpt)(1p)(H2O)(2)](n) 2nH(2)O (3), and [Cu-2(3-abpt)(2)(C6H5COO)(4)(H2O)(2)](n) 2nH(2)O (4) (ip = isophthalate, beta = 1,2,4,5-benzenetetracarboxylate). Compound 1 is a 3D coordination polymer with uncommon 3,4-connected (6(2),8)(2)(6(2),8(2) 10(2)) network Compounds 2-4 are all 1D coordination polymers, which exhibit diversity structures Compound 2 is a tubular-like chain. 3 is a ring-like network, and 4 is a zigzag chain. Their thermal stabilities and the photoluminescence of 1 have also been investigated. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1062 / 1068
页数：7
相关论文
共 50 条
  • [1] Syntheses, structures and thermal stabilities of four complexes with 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand
    Liu, Jing-Jing
    He, Xiang
    Shao, Min
    Li, Ming-Xing
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2008, 891 (1-3) : 50 - 57
  • [2] Syntheses and topological networks of two azide complexes based on 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligands
    Liu, Jing-Jing
    He, Xiang
    Shao, Min
    Li, Ming-Xing
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (10) : 972 - 974
  • [3] 4-amino-3,5-bis(4-pyridyl)-1,2,4-triazole
    Guo, YM
    Du, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2002, 58 : O966 - O968
  • [4] Four coordination polymers derived from 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole and copper sulfate
    Liu, Kui
    Zhu, Xia
    Wang, Ju
    Li, Baolong
    Zhang, Yong
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (08) : 976 - 980
  • [5] Syntheses and Crystal Structures of Co(II) and Cu(II) Complexes Based on 3,5-Bis(3-pyridyl)-4-amino-1,2,4-triazole Ligand
    Yu Qin
    Wang Da-Peng
    Ma Jian-Ping
    Yu Fei
    Cao Zi-Heng
    Hu Tian-Hao
    Wang Peng
    Wang Hai-Ying
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2017, 33 (12) : 2345 - 2350
  • [6] Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis-(hydroxymethyl)-1,2,4-triazole] nickel(II)} tetranitrate methanol disolvate
    Pan, Yu-Peng
    Li, Da-Cheng
    Wang, Da-Qi
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M96 - U933
  • [7] PREPARATION OF 4-AMINO-3,5-BIS (OMEGA-AMINOALKYL)-1,2,4-TRIAZOLE
    TANIYAMA, M
    OKAUCHI, T
    NAGAOKA, T
    TAKATA, T
    [J]. KOGYO KAGAKU ZASSHI, 1961, 64 (09): : 1626 - &
  • [8] THE REACTION OF 4-AMINO-3,5-BIS[METHYLTHIO]-1,2,4-TRIAZOLE WITH ALKYLATING REAGENTS
    MOLINA, P
    ALAJARIN, M
    [J]. SYNTHESIS-STUTTGART, 1983, (05): : 414 - 415
  • [9] 4-Amino-3,5-bis(1-hydroxyethyl)-4H-1,2,4-triazole
    Li, Kao-Zhen
    He, Qing-Peng
    Li, Rong-Shan
    Wang, Da-Qi
    Lu, Ze-Hua
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O3908 - U3931
  • [10] Synthesis, Structures, and Properties of NiII, CoII, CuII, MnII, and ZnII Coordination Polymers Based on 5-Aminoisophthalate and 4-Amino-3,5-bis (3-pyridyl)-1,2,4-triazole
    Hu, Xiao-Dan
    Guo, Ya-Mei
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (04) : 522 - 528
12345