The effect of an alkylsilane monolayer on an indium-tin oxide surface on the electrochemistry of hexacyanoferrate

被引：49

作者：

Markovich, I ^{[1
]}

Mandler, D ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91904 Jerusalem, Israel

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2000年 / 484卷 / 02期

关键词：

cyclic voltammetry; electron transfer; indium-tin oxide; self-assembled monolayer; hexacyanoferrate; redox potential;

D O I：

10.1016/S0022-0728(00)00084-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The presence of a disorganized octadecylsilane, C-18, monolayer on an indium-tin oxide (ITO) electrode has a profound effect on the electrochemistry of hexacyanoferrate, Fe(CN)(6)(3-/4-). We found that the alkylsilane monolayer forms a hydrophobic matrix, which affects the heterogeneous rate of electron transfer of the metallic complex, depending on the nature of the counter cation presence in the solution. A model is suggested which accounts for these effects as well as for the changes in the formal redox potential that are observed. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：194 / 202

页数：9

共 50 条

[1] Electrochemistry of the indium-tin oxide electrode in 1 M NaOH electrolyte
Matveeva, E
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (09) : H138 - H145
[2] Synthesis and Electrochemistry of 6 nm Ferrocenated Indium-Tin Oxide Nanoparticles
Roberts, Joseph J. P.
Vuong, Kim T.
Murray, Royce W.
[J]. LANGMUIR, 2013, 29 (01) : 474 - 479
[3] Redox and photochemical behaviour of a porphyrin monolayer on an indium-tin oxide electrode
Araki, N
Obata, M
Ichimura, A
Amao, Y
Mitsuo, K
Asai, K
Yano, S
[J]. ELECTROCHIMICA ACTA, 2005, 51 (04) : 677 - 683
[4] Sputtering of indium-tin oxide
Howson, RP
Safi, I
Hall, GW
Danson, N
[J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1997, 121 (1-4): : 96 - 101
[5] Effect of Different Pretreatments on Indium-Tin Oxide Electrodes
Choi, Moonjeong
Jo, Kyungmin
Yang, Haesik
[J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2013, 34 (02): : 421 - 425
[6] Structural Effect on Formation of Alkylsilane Self-Assembled Monolayers on Indium Tin Oxide Surface
Choi, Youngsik
Noh, Jaegeun
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2008, 492 : 165 - 171
[7] Flexible Indium-Tin Oxide Crystal on Plastic Substrates Supported by Graphene Monolayer
Lee, Sang Jin
Kim, Yekyung
Hwang, Jun-Yeon
Lee, Ju-Ho
Jung, Seungon
Park, Hyesung
Cho, Seungmin
Nahm, Sahn
Yang, Woo Seok
Kim, Hyeongkeun
Han, Seung Ho
[J]. SCIENTIFIC REPORTS, 2017, 7
[8] Surface characteristics of indium-tin oxide cleaned by remote plasma
Kim, S
Seo, H
Kim, Y
Kim, K
Tak, Y
Jeon, H
[J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (02): : 1041 - 1044
[9] Indium-tin oxide organic interfaces
Donley, CL
Dunphy, DR
Doherty, WJ
Zangmeister, RAP
Drager, AS
O'Brien, DF
Saavedra, SS
Armstrong, NR
[J]. MOLECULES AS COMPONENTS OF ELECTRONIC DEVICES, 2003, 844 : 133 - 153
[10] Effect of substrate temperature on the surface structure, composition and morphology of indium-tin oxide films
de Carvalho, CN
do Rego, AMB
Amaral, A
Brogueira, P
Lavareda, G
[J]. SURFACE & COATINGS TECHNOLOGY, 2000, 124 (01): : 70 - 75

← 1 2 3 4 5 →