Synthesis, Characterization, and Crystal Structures of [Cu(phen)2Cl]Cl. 6.5H2O and [Cu(phen)2Br]Br

被引：14
|
作者：
Onawumi, O. O. [1 ]
Adekunle, F. A. [1 ]
Ibrahim, A. O. [1 ]
Rajasekharan, M. V. [2 ]
Odunola, O. A. [1 ]
机构：
[1] Ladoke Akintola Univ Technol, Dept Pure & Appl Chem, Ogbomosho, Nigeria
[2] Univ Hyderabad, Sch Chem, Hyderabad 500134, Andhra Pradesh, India
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2010年 / 40卷 / 02期
关键词：
synthesis; mixed-ligands; x-ray; electron spin resonance; electronic spectra; ELECTRONIC-PROPERTIES; COMPLEXES; STEREOCHEMISTRY;
D O I：
10.3109/10799890903555673
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two mixed-ligand complexes of copper(II) with 1,10-phenanthroline and halides [Cu(phen)(2)Cl]Cl.6.5H(2)O (1) and [Cu(phen)(2) Br]Br(2), have been synthesized and characterized by microanalysis, spectroscopic, magnetic and single-crystal X-ray diffraction studies. The two complexes are isostructural in which the coordination geometry about the copper(II) ion is that of a trigonal bipyramid, with the central copper atom bound to one chloride (I) and one bromide (2) atom and four nitrogen atoms of the two phenanthroline ligands. The result of IR, electronic spectra, electron spin resonance (ESR) and magnetic measurements are discussed.
引用
收藏
页码：78 / 83
页数：6
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