Microwave-Assisted Dibromoolefination of Aromatic and Heteroaromatic Aldehydes and Ketones

被引：3
|
作者：
Nauroozi, Djawed [2 ]
Bruhn, Clemens
Fuermeier, Sven
Holzhauer, Joern-Uwe
Faust, Ruediger [1 ]
机构：
[1] Univ Kassel, Inst Chem, Heinrich Plett Str 40, D-34132 Kassel, Germany
[2] Inst Organ Chem II & Neue Mat, Albert Einstein Allee 11, D-89081 Ulm, Germany
来源：
JOURNAL OF HETEROCYCLIC CHEMISTRY | 2016年 / 53卷 / 02期
关键词：
TRIPHENYLPHOSPHINE; DERIVATIVES;
D O I：
10.1002/jhet.2332
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Microwave (MW) irradiation was successfully employed to convert aromatic and heteroaromatic aldehydes and ketones efficiently to the corresponding dibromoolefins. Exemplified by the successful dibromoolefination of traditionally inert pyridyl-flanked carbonyls, MW activation significantly broadens the scope of this valuable transformation, although some limitations especially with electron-rich aromatic ketone derivatives remain.
引用
收藏
页码：615 / 619
页数：5
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