Electrocatalytic reduction of dioxygen to water by a carbon electrode coated with (η-oxo)bis[(meso-tetraphenylporphyrinato)iron(III)]:: a convenient template for cofacially oriented iron(II) porphyrins

被引：0

作者：

Haryono, A ^{[1
]}

Oyaizu, K ^{[1
]}

Yamamoto, K ^{[1
]}

Natori, J ^{[1
]}

Tsuchida, E ^{[1
]}

机构：

[1] Waseda Univ, Dept Polymer Chem, Adv Res Inst Sci & Engn, Tokyo 1698555, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 03期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electroreduction of an ore-bridged iron(III) porphyrin dimer adsorbed on an electrode surface produced solid state, cofacially fixed two iron(II) porphyrin molecules when immersed in aqueous acid, allowing an efficient catalysis of the four-electron reduction of O-2 to H2O.

引用

页码：233 / 234

页数：2

共 5 条

[1] OXIDATION OF RUTHENIUM(II) AND RUTHENIUM(III) PORPHYRINS - CRYSTAL-STRUCTURES OF MU-OXO-BIS[(PARA-METHYLPHENOXO)(MESO-TETRAPHENYLPORPHYRINATO)-RUTHENIUM(IV)] AND ETHOXO(MESO-TETRAPHENYLPORPHYRINATO)-(ETHANOL)RUTHENIUM(III)-BISETHANOL
COLLMAN, JP
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[2] ELECTRON-TRANSFER BETWEEN BIS(PYRIDINE)MESO-TETRAPHENYLPORPHYRINATO IRON(II) AND RUTHENIUM(III) AND THE HEXACYANOFERRATE COUPLE AT THE 1,2-DICHLOROETHANE WATER INTERFACE
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[3] Electrocatalytic Behavior of a Carbon Paste Electrode Modified with Iron(III)tetracyanophenylporphyrin Chloride Towards Dioxygen Reduction
Shamsipur, M.
Najafi, M.
Hosseini, M. R. Milani
Sharghi, H.
Kazemi, S. H.
[J]. POLISH JOURNAL OF CHEMISTRY, 2009, 83 (06) : 1173 - 1183
[4] Electroreduction of μ-oxo iron(III) porphyrins adsorbed on an electrode leading to a cofacial geometry for the iron(II) complex:: Unexpected active site for the catalytic reduction of O2 to H2O
Oyaizu, K
Haryono, A
Natori, J
Shinoda, H
Tsuchida, E
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (05) : 1153 - 1163
[5] Electroreduction of μ-oxo iron(III) porphyrins adsorbed on an electrode leading to a cofacial geometry for the iron(II) complex: Unexpected active site for the catalytic reduction of O2 to H2O
[J]. 1600, (Chemical Soc of Japan, Tokyo, Japan):

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