Effect of ZnS nanowire ARC on CZTS/CdS thin film solar cell by Nebulizer Spray Pyrolysis Technique

The main intention of this experimental work is to eliminate the reflection of the CZTS/CdS thin film solar cell by depositing the ZnS Antireflection coating (ARC) by Nebulizer Spray Pyrolysis Technique. The CZTS/CdS thin films with and without ZnS Antireflection coating (ARC) deposited using nebulizer spray pyrolysis method is reported in this work. The prepared films were characterized by X-ray diffraction, scanning electron microscopy and UV-Vis spectroscopy analysis. Structural parameters such as lattice constants, texture orientation factor, micro strain, dislocation density and crystallite size were estimated using XRD data. The efficiency of CZTS/CdS solar cell is calculated using I-V characteristics. The experimental results exhibit the short circuit current increased from 9.269 x 10(-5)A to 1.250 x 10(-4)A and efficiency raised from 0.21% to o.45%. with ZnS as a ARC. The theoretical quantum efficiency of CZTS solar cell with ZnS ARC is increased from 0.020% to 0.030%. The results indicates that the ZnS ARC is one of the perfect ARC in the CZTS solar cell.