Transition-Metal-Free, Visible-Light-Enabled Decarboxylative Borylation of Aryl N-Hydroxyphthalimide Esters

被引：287

作者：

Candish, Lisa ^{[1
]}

Teders, Michael ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Westfal Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2017年 / 139卷 / 22期

关键词：

CATALYZED DECARBONYLATIVE BORYLATION; COUPLING REACTIONS; CARBOXYLIC-ACIDS; BENZOIC-ACIDS; BOND; N-(ACYLOXY)PHTHALIMIDES; FUNCTIONALIZATIONS; ACTIVATION; CHEMISTRY; ARYLATION;

D O I：

10.1021/jacs.7b03127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report a conceptually novel borylation reaction proceeding via a mild photoinduced decarboxylation of redox-activated aromatic carboxylic acids. This work constitutes the first application of cheap, and easily prepared N-hydroxyphthalimide esters as aryl radical precursors and does not require the use of expensive transition metals or ligands. The reaction operationally simple, scalable, and displays broad scope and functional group tolerance.

引用

页码：7440 / 7443

页数：4

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