Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes

被引：0
|
作者：
Ansell, Melvyn B. [1 ]
Kostakis, George E. [1 ]
Navarro, Oscar [1 ,2 ]
Spencer, John [1 ]
机构：
[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England
[2] AMPAC Fine Chem, Highway 50 & Hazel Ave,Bldg 05-019, Rancho Cordova, CA 95741 USA
来源：
MOLECULES | 2021年 / 26卷 / 09期
基金：
英国工程与自然科学研究理事会;
关键词：
palladium; silicon; N-heterocyclic carbene; allylsilane; PINCER; REACTIVITY; HALIDES; LIGAND; PSIP; PD;
D O I：
10.3390/molecules26092460
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The stoichiometric reaction of cis-[Pd(ITMe)(2)(SiR3)(2)], where (SiR3 = SiMe3 and SiMe2Ph and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type trans-[Pd(ITMe)(2)(SiR3)(Br)]. The structure of trans-[Pd(ITMe)(2)(SiMe2Ph)Br] 2b has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a trans-configuration.
引用
收藏
页数：6
相关论文
共 50 条
  • [1] SYNTHESIS OF MONO(SILYL) AND BIS(SILYL) COMPLEXES OF TANTALUM
    JIANG, Q
    CARROLL, PJ
    BERRY, DH
    ORGANOMETALLICS, 1991, 10 (10) : 3648 - 3655
  • [2] Reactions of bis(silyl)palladium(II) complexes with allyl halides.: Synthesis of mono(silyl)palladium(II) halides and X-ray structure of trans-PdCl(SiF2Ph)(PMe2Ph)2
    Ozawa, F
    Sugawara, M
    Hasebe, K
    Hayashi, T
    INORGANICA CHIMICA ACTA, 1999, 296 (01) : 19 - 25
  • [3] REACTION OF PALLADIUM(II) COMPLEXES WITH ALLYLSILANES - CONVENIENT SYNTHESIS OF [ETA-3-1-(SILYL)ALLYL]PALLADIUM COMPLEXES
    OGOSHI, S
    YOSHIDA, W
    OHE, K
    MURAI, S
    ORGANOMETALLICS, 1993, 12 (02) : 578 - 579
  • [4] Synthesis, characterisation and absorption spectroscopy of mono and dinuclear complexes of platinum(II) and palladium(II)
    Anbalagan, V
    Srivastava, TS
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2000, 39 (06): : 667 - 671
  • [5] ACETYLENE ACTIVATION BY PALLADIUM (II) BROMIDE COMPLEXES
    SOKOLSKI.DV
    SEGIZBAE.SS
    DORFMAN, YA
    ZHURNAL ORGANICHESKOI KHIMII, 1970, 6 (05): : 893 - &
  • [6] SYNTHESIS AND CHARACTERIZATION OF MONO(SILYL)IRIDIUM AND BIS(SILYL)IRIDIUM BIS(PHOSPHINE) COMPLEXES
    HAYS, MK
    EISENBERG, R
    INORGANIC CHEMISTRY, 1991, 30 (12) : 2623 - 2630
  • [7] trans-Difluoro Complexes of Palladium(II)
    Grushin, Vladimir V.
    Marshall, William J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (03) : 918 - +
  • [8] KINETICS OF REACTIONS OF ALKYLIODIDES WITH BROMIDE PALLADIUM(II) COMPLEXES
    LITVINENKO, SL
    ZAMASHCHIKOV, VV
    RUDAKOV, ES
    STRELTSOV, VI
    UKRAINSKII KHIMICHESKII ZHURNAL, 1981, 47 (02): : 186 - 188
  • [9] SYNTHESIS AND STRUCTURE OF PALLADIUM(II) TRANS-COMPLEXES WITH N-METHYLPIPERAZINE
    IVANOVA, NA
    KURBAKOVA, AP
    EROFEEV, VV
    KUZMINA, LG
    PORAIKOSHITS, MA
    EFIMENKO, IA
    ZHURNAL NEORGANICHESKOI KHIMII, 1991, 36 (11): : 2821 - 2827
  • [10] Synthesis, Characterization and Biological Studies of Organoselenium trans-Palladium(II) Complexes
    Rakovic, Ivana
    Bogojeski, Jovana
    Mladenovic, Katarina
    Petrovic, Angelina
    Divac, Vera
    Mihailovic, Kristina
    Jovicic, Biljana Popovska
    Kostic, Marina
    Canovic, Predrag
    Milivojevic, Nevena
    Zivanovic, Marko
    Radojevic, Ivana
    MEDICINAL CHEMISTRY, 2021, 17 (09) : 1007 - 1022
12345