Ordered Semiconducting Self-Assembled Monolayers on Polymeric Surfaces Utilized in Organic Integrated Circuits

被引:34
|
作者
Gholamrezaie, Fatemeh [1 ,2 ]
Mathijssen, Simon G. J. [2 ,3 ]
Smits, Edsger C. P. [4 ]
Geuns, Tom C. T. [2 ]
van Hal, Paul A. [2 ]
Ponomarenko, Sergei A. [5 ]
Flesch, Heinz-Georg [6 ]
Resel, Roland [6 ]
Cantatore, Eugenio [3 ]
Blom, Paul W. M. [1 ,4 ]
de Leeuw, Dago M. [1 ,2 ]
机构
[1] Univ Groningen, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands
[2] Philips Res Labs, NL-5656 AE Eindhoven, Netherlands
[3] Eindhoven Univ Technol, NL-5600 MB Eindhoven, Netherlands
[4] Holst Ctr TNO, NL-5656 AE Eindhoven, Netherlands
[5] Russian Acad Sci, Enikolopov Inst Synthet Polymer Mat, Moscow 117393, Russia
[6] Graz Univ Technol, Inst Solid State Phys, A-8010 Graz, Austria
关键词
Self-assembled monolayer field-effect transistors; self-assembly; organic integrated circuits; liquid crystal; organic dielectric; TRANSISTORS; ADSORPTION;
D O I
10.1021/nl9032268
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report on a two-dimensional highly ordered self-assembled monolayer (SAM) directly grown on a bare polymer surface. Semiconducting SAMs are utilized in field-effect transistors and combined into integrated circuits as 4-bit code generators. The driving force to form highly ordered SAMs is packing of the liquid crystalline molecules caused by the interactions between the linear alkane moieties and the pi-pi stacking of the conjugated thiophene units. The fully functional circuits demonstrate long-range order over large areas, which can be regarded as the start of flexible monolayer electronics.
引用
收藏
页码:1998 / 2002
页数:5
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