Platinum-catalyzed amidocarbonylation

被引：12

作者：

Sagae, T ^{[1
]}

Sugiura, M ^{[1
]}

Hagio, H ^{[1
]}

Kobayashi, S ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 02期

关键词：

D O I：

10.1246/cl.2003.160

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of platinum-catalyzed amidocarbonylation of aldehydes with amides and carbon monoxide is described. In contrast to precedent palladium catalysis, a remarkable ligand acceleration by phosphines was observed. Furthermore, an optically active N-acetyl amino acid was partially epimerized under the platinum-catalyzed conditions, while faster racemization was observed under the palladium catalysis.

引用

页码：160 / 161

页数：2

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