Chiral imidazolylidine ligands for asymmetric catalysis

被引：0

作者：

Burgess, K ^{[1
]}

Perry, MC ^{[1
]}

Cui, XH ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

METHODOLOGIES IN ASYMMETRIC CATALYSIS | 2004年 / 880卷

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combination of a small library of oxazoline electrophiles and imidazole nucleophiles led to the formation of a significant number of chiral imidazolium salts. Iridium and rhodium complexes were synthesized from these by the treatment with lithium tert-butoxide in the presence of [Ir(COD)Cl](2) or [Rh(NBD)(2+)[BF(4)]. These complexes were screened in the hydrogenation of unfunctionalized alkenes.

引用

页码：61 / 84

页数：24

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