Biodiesel production using cation-exchange resin as heterogeneous catalyst

被引：149

作者：

Feng, Yaohui ^{[1
]}

He, Benqiao ^{[1
]}

Cao, Yuhe ^{[1
]}

Li, Jianxin ^{[1
]}

Liu, Meng ^{[1
]}

Yan, Feng ^{[1
]}

Liang, Xiaoping ^{[1
]}

机构：

[1] Tianjin Polytech Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Hollow Fiber Membrane Mat & Proc, Tianjin 300160, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2010年 / 101卷 / 05期

关键词：

Cation-exchange resin; Biodiesel; Esterification; Acidified oil; FREE FATTY-ACIDS; ACETIC-ACID; ESTERIFICATION; 1-BUTANOL; OILS;

D O I：

10.1016/j.biortech.2009.07.084

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Three types of cation-exchange resins (NKC-9, 001 x 7 and D61) as solid acid catalysts were employed to prepare biodiesel from acidified oils generated from waste frying oils. The results show that the catalytic activity of NKC-9 was higher than that of 001 x 7 and D61. The conversion of the esterification by NKC-9 increased with increasing in the amount of catalyst, reaction temperature and time and methanol/oil molar ratio. The maximal conversion of reaction is approximately 90.0%. Furthermore, NKC-9 resin exhibits good reusability. Gas chromatography-mass spectrometry analysis reveals that the production is simplex and mainly composed of C16:0 (palmitic), C18:2 (linoleic), and C18:1 (oleic) acids of methyl ester, respectively. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1518 / 1521

页数：4

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