Analysis of Mullite Formation in the Core Glass of a Chromium-Doped Aluminosilicate Fiber

被引:3
|
作者
Abramov, A. N. [1 ]
Plekhovich, A. D. [1 ]
Kut'in, A. M. [1 ]
Yashkov, M. V. [1 ]
Guryanov, A. N. [1 ]
机构
[1] Russian Acad Sci, Devyatykh Inst Chem High Pur Subst, Ul Tropinina 49, Nizhnii Novgorod 603951, Russia
基金
俄罗斯基础研究基金会;
关键词
mullite; glass-ceramic; Gibbs energy; silica glass; optical fiber; differential scanning calorimetry;
D O I
10.1134/S0020168518090017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Using MCVD, we have produced optically active fibers with a glass-ceramic core containing mullite, 3Al(2)O(3) <bold> </bold>2SiO(2), as a major crystalline phase. Thermodynamic prediction of mullite formation conditions has been supplemented by thermal analysis and X-ray diffraction characterization of preform core samples, and fiber heat treatment (annealing) conditions have been established. Luminescence measurements for the fibers annealed under optimal conditions demonstrate that optically active chromium has a crystalline local environment.
引用
收藏
页码:940 / 948
页数:9
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