Recent advances in the substitution reactions of thriorganylstannyl ions with aromatic compounds by the SRN1 mechanism.: Synthetic applications

被引:2
|
作者
Córsico, EF [1 ]
Postigo, A [1 ]
Rossi, RA [1 ]
机构
[1] Univ Nacl Cordoba, Fac Ciencias Quim, Dept Quim Organ, INFIQC, RA-5000 Cordoba, Argentina
来源
MOLECULES | 2000年 / 5卷 / 09期
关键词
stannyl anions; S(RN)1; Stille reactions;
D O I
10.3390/50901068
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A review on the reactions of triorganyl stannyl ions with haloarenes is presented Emphasis on the synthetic applications of the resulting triorganyl stannyl aryl compounds is made, with their inherent potential to build large molecules through the S(RN)1 sequence,i.e. ArX-->ArSnR3-->ArAr, which can be iteratively repeated when appropriately substituted substrates are chosen.
引用
收藏
页码:1068 / 1079
页数:12
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