P[N(i-Bu)CH2CH2]3N:: A versatile ligand for the Pd-catalyzed amination of aryl chlorides

被引:84
|
作者
Urgaonkar, S [1 ]
Nagarajan, M [1 ]
Verkade, JG [1 ]
机构
[1] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA
关键词
D O I
10.1021/ol027450b
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Graphics Palladium-catalyzed amination reactions of aryl chlorides with amines proceeded in the presence of the bicyclic triaminophosphine P[N(i-Bu)CH2CH2](3)N to afford the corresponding arylamines in good to excellent yields. Electron-poor, electron-neutral, and electron-rich aryl chlorides all participated with equal ease.
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页码:815 / 818
页数:4
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