Hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene over Ni-Mo catalysts supported by siliceous SBA-15

被引:0
|
作者
Ren, Jing [1 ]
Wang, Anjie [1 ]
Tan, Juan [1 ]
Cao, Guangwei [1 ,2 ]
Liu, Chang [2 ]
Li, Yongtai [2 ]
Lu, Mohong [1 ]
Hu, Yongkan [1 ,2 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, 158 Zhongshan Rd, Dalian 116012, Peoples R China
[2] Fushun Res Inst Petr & Petrochem, Fushun 113001, Peoples R China
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中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A deep hydrodesulfurization (HDS) catalyst, which was considerably active to desulfurize dibenzothiophene (DBT) and 4, 6-dimethyldibenzothiophene (4,6-DMDBT), was prepared by depositing Ni-Mo species over SBA-15. The extremely high surface area of SBA-15 favors the dispersion of the active species, which result in very high HDS activity. The optimal Ni/Mo atomic ratio for this series of catalysts is 0.25. Ni-Mo(0.25)/SBA-15 exhibited excellent performance in HDS of DBT and 4,6-DMDBT.
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页码:721 / 724
页数:4
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