One-pot amidation of olefins through Pd-catalyzed coupling of alkylboranes and carbamoyl Chlorides

被引：31
|
作者：
Yasui, Yoshizumi [1 ]
Tsuchida, Sayo [1 ]
Miyabe, Hideto [1 ]
Takemoto, Yoshiji [1 ]
机构：
[1] Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 15期
关键词：
D O I：
10.1021/jo070724u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A one-pot synthesis of C-1-elongated amides starting from olefins and carbamoyl chlorides has been developed. Alkylboranes, generated by hydroboration of terminal olefins with 9-BBN-H, underwent smooth coupling with carbamoyl chlorides in the presence of palladium catalyst and Cs2CO3.
引用
收藏
页码：5898 / 5900
页数：3
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