Regioselective rhodium-catalyzed allylic alkylation with a modified Wilkinson's catalyst

被引：87

作者：

Evans, PA ^{[1
]}

Nelson, JD ^{[1
]}

机构：

[1] Univ Delaware, Dept Chem & Biochem, Brown Lab, Newark, DE 19716 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(98)00142-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of the secondary and tertiary allylic carbonates 1 with the sodium salt of dimethyl malonate and a catalytic amount of Wilkinson's catalyst modified with a triorganophosphite, furnished the tertiary and quaternary carbon stereogenic centers 2 in high yield with excellent regioselectivity. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1725 / 1728

页数：4

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