Kinetics of leaching selenium from Ni-Mo ore smelter dust using sodium chlorate in a mixture of hydrochloric and sulfuric acids

The kinetics of leaching selenium from Ni-Mo ore smelter dust in H2SO4-HCI-H2O system was investigated. The effects including leaching temperature and time, particle size of the smelting dust, stirring speed, acid concentration and the coefficient beta (the molar ratio of sodium chlorate to selenium in the smelter dust) on leaching of selenium were studied. The results indicated that the leaching of selenium increased sharply with the increase of temperature. The leaching of selenium reached 98% at 95 degrees C and stirring speed of 350 rpm for 150 min with the particle size of -0.15 mm. initial [H-4(-)] concentration of 8 mol/L, the solid/liquid ratio of 1:5 g/mL and the coefficient beta of 3.33. The leaching process was controlled by the surface chemical reaction and the kinetics of leaching selenium from Ni-Mo ore smelter dust followed the model of "shrinking core". The apparent activation energy of leaching selenium was determined to be 44.4 kJ/mol, which was consistent with the values of activation energy reported for the surface chemical reaction control. The kinetics equation of leaching selenium from Ni-Mo ore smelter dust was expressed as 1-(1-eta)(1/3) = 185.4 exp(-44400/RT)t, which coincided with the experimental results. (C) 2010 Elsevier B.V. All rights reserved.