Comparative Study on Hole Transport in N,N′-bis(naphthalen-1-yl)-N,N′-bis(pheny) Benzidine and 4, 4′, 4"-tri(N-carbazolyl)triphenylamine
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作者:
Qiao Xian-Feng
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Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Qiao Xian-Feng
[1
,2
]
Chen Jiang-Shan
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Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Chen Jiang-Shan
[1
]
Ma Dong-Ge
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Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Ma Dong-Ge
[1
]
机构:
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Hole transport characteristics in N,N'-bis(naphthalen-1-yl)-N,N'-bis(pheny) benzidine (NPB) and 4, 4', 4 ''-tri(N-carbazolyl)triphenylamine (TCTA) are comparatively investigated. The current density-voltage (J - V) characteristics of hole-only devices based on NPB and TCTA at different temperatures and thicknesses show that the hole current is dominated by the bulk conduction with an exponential trap distribution. Detailed analyses of the J - V characteristics give the trap densities N-t of (6.3 +/- 0.3) x10(18) and (1.9 +/- 0.02) x10(18) cm(3), characteristic trap depths of 135 +/- 6 and 117 +/- 5 meV, hole mobilities of (8.1 +/- 0.5) x 10(-5) and (1.9 +/- 0.1) x 10(-4) cm(2) V-1 s(-1) for NPB and TCTA, respectively. It is found that TCTA exhibits higher hole mobility. Obviously, this is directly related to the lower trap density and shallow trap depth in TCTA films, leading to good charge carrier transport.
机构:
Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Li Bi-Xin
Chen Jiang-Shan
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Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Chen Jiang-Shan
Zhao Yong-Biao
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Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Zhao Yong-Biao
Ma Dong-Ge
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Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R ChinaChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
机构:
Okinawa Inst Sci & Technol Grad Univ OIST, Energy Mat & Surface Sci Unit EMSS, 1919-1 Tancha, Onna Son, Okinawa 9040495, JapanOkinawa Inst Sci & Technol Grad Univ OIST, Energy Mat & Surface Sci Unit EMSS, 1919-1 Tancha, Onna Son, Okinawa 9040495, Japan