A novel three dimensional 3d-4f heterometallic coordination framework with 2, 2′-bipyridine-3-carboxylate and oxalate ligands

被引：24
|
作者：
Tang, Yun-Zhi [1 ]
Wen, He-Rui [1 ]
Cao, Zan [1 ]
Wang, Xiao-Wei [1 ]
Huang, Shuai [1 ]
Yu, Chang-Lin [1 ]
机构：
[1] Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn, Ganzhou 341000, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期
关键词：
Heterometallic polymer; Hydrothermal synthesis; Neodymium complex; Copper complex; COMPLEXES; HHFAC; GD;
D O I：
10.1016/j.inoche.2010.04.027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The 3D heterometallic polymeric complex 1 {[Nd2Cu2(L)(2)(OXA)(4)center dot 2(2H(2)O)]center dot 2(3H(2)O)}(n) (HL = 2, 2'-bipyridine-3-carboxyic acid, OXA = oxalate) was obtained from hydrothermal reaction of Nd2O3, Cu(ClO4)(2), HL and oxalic acid in the presence of ethanol and water. X-ray single crystal diffraction investigation of the polymeric complexes {[Nd2Cu2(L)(2)(OXA)(4)center dot 2(2H(2)O)]center dot 2(3H(2)O)}(n) exhibits an interesting and novel topological structure. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：924 / 928
页数：5
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