Synthesis of imidazolium and pyridinium-based ionic liquids and application of 1-alkyl-3-methylimidazolium salts as pre-catalysts for the benzoin condensation using solvent-free and microwave activation

被引：91

作者：

Aupoix, Audrey ^{[1
]}

Pegot, Bruce ^{[2
]}

Vo-Thanh, Giang ^{[1
]}

机构：

[1] Univ Paris 11, Lab Catalyse Mol, Inst Chim Mol & Mat Orsay, UMR 8182, F-91405 Orsay, France

[2] Univ Versailles, UMR 8086, Inst Lavoisier Franklin, F-78035 Versailles, France

来源：

TETRAHEDRON | 2010年 / 66卷 / 06期

关键词：

ASSISTED ORGANIC-SYNTHESIS; FREE ROUTE; EFFICIENT; THIAZOLIUM; TRANSFORMATIONS;

D O I：

10.1016/j.tet.2009.11.110

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient one-pot procedure for the synthesis of ionic liquids based on nitrogen-containing heterocycles, imidazolium or pyridinium under 'green chemistry' conditions has been described Imidazolium salts and DBU have been found to catalyze efficiently the berizoin condensation giving good yields within very short reaction time using solvent-free microwave activation conditions (C) 2009 Elsevier Ltd All rights reserved

引用

页码：1352 / 1356

页数：5

共 5 条

[1] Solventless and swift benzoin condensation catalyzed by 1-alkyl-3-methylimidazolium ionic liquids under microwave irradiation
Estager, Julien
Leveque, Jean-Marc
Turgis, Raphael
Draye, Micheline
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 256 (1-2) : 261 - 264
[2] Solvent-Free Sonochemical Synthesis and Antifungal Activity of 1-Alkyl-3-Methylimidazolium Bromide [RMIM]Br Ionic Liquids
Perez, Ser John Lynon P.
Arco, Susan D.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2014, 61 (08) : 935 - 939
[3] Synthesis of functionalized chiral ammonium, imidazolium, and pyridinium-based ionic liquids derived from (-)-ephedrine using solvent-free microwave activation. Applications for the asymmetric Michael addition
Truong, Thi-Kim-Thu
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TETRAHEDRON, 2010, 66 (27-28) : 5277 - 5282
[4] Microwave-assisted Fischer indole synthesis of 1,2,3,4-tetrahydrocarbazole using pyridinium-based ionic liquids
Eduque, Ramon M., Jr.
Creencia, Evelyn C.
INTERNATIONAL SYMPOSIUM ON APPLIED CHEMISTRY 2015, 2015, 16 : 413 - 419
[5] The molar surface Gibbs free energy and its application 2: Ionic liquids 1-alkyl-3-methylimidazolium threonine salts [Cnmim][Thr] (n=2, 4) at T = (288.15 to 328.15) K
Tong, Jing
Wang, Lin-Fu
Liu, Da-Liang
Chen, Teng-Fei
Tong, Jian
Yang, Jia-Zhen
JOURNAL OF CHEMICAL THERMODYNAMICS, 2016, 97 : 228 - 234

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