Structure, reactivity, and selectivity of metal-peroxo complexes versus dioxiranes

被引：0
|
作者：
Adam, W [1 ]
Mitchell, CM [1 ]
Saha-Möller, CR [1 ]
Weichold, O [1 ]
机构：
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
来源：
METAL-OXO AND METAL-PEROXO SPECIES IN CATALYTIC OXIDATIONS | 2000年 / 97卷
关键词：
peroxo complexes; dioxiranes; oxygen transfer; reactivity; chemoselectivity; regioselectivity; diastereoselectivity; enantioselectivity;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dioxiranes, MTO/H2O2, and MTO/UHP are becoming increasingly important as efficient and selective oxidants in organic chemistry and numerous publications have appeared on each of them. Here we present a comprehensive review, comparing the chemistry of these reagents with particular emphasis on the oxidation of pi bonds, heteroatoms, and sigma bonds. We will discuss structural aspects and on this basis, will outline the reactivity and selectivity of these oxidants, along, with the mechanistic aspects of the oxygen-transfer process.
引用
收藏
页码：237 / 285
页数：49
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