The molecular structure of (PSH+)(nido-7,8-C2B9H12-) determined by neutron diffraction (PS = proton sponge, 1,8-bis(dimethylamino)naphthalene)

被引：40
|
作者：
Fox, MA
Goeta, AE
Howard, JAK
Hughes, AK
Johnson, AL
Keen, DA
Wade, K
Wilson, CC
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Rutherford Appleton Lab, CLRC, ISIS, Didcot OX11 0QX, Oxon, England
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 01期
关键词：
D O I：
10.1021/ic000961e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A neutron diffraction study of the salt (PSH+)(nido-7 8-C2B9H12-) reveals the unsymmetrically bridging site of the endo hydrogen in the carborane anion. This is the first neutron diffraction structure determination of a cluster borane or carborane containing natural abundance boron isotopes.
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页码：173 / +
页数：4
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