Novel carbon molecular sieve honeycomb membrane module: configuration and membrane characterization

被引:14
|
作者
Lagorsse, S
Leite, A
Magalhaes, FD
Bischofberger, N
Rathenow, J
Mendes, A
机构
[1] Univ Porto, Fac Engn, Dept Engn Quim, LEPAE, P-4200465 Oporto, Portugal
[2] Blue Membranes GmbH, D-65203 Wiesbaden, Germany
关键词
molecular sieve; heat treatment; adsorption; porosity; transport properties;
D O I
10.1016/j.carbon.2004.11.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new production concept of carbon molecular sieve membranes modules is described. The supported membrane synthesis process allows for industrial production with uniform and reproducible properties, using flat membranes as a starting precursor. The corresponding membrane modules are made in a honeycomb configuration, leading to high packing density and thermochemical stability. Some of the carbon membranes produced for use in these modules are characterized. Species H-2, O-2, N-2, CO2 and SF6 were used in monocomponent adsorption and permeation experiments to obtain adsorption equilibrium and permeation data. High permeabilities were attained in combination with high selectivities. The pore size distribution of the membrane was determined. A number of complementary morphological and structural characterizations were also performed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:809 / 819
页数:11
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