Functionalized polystyrene based single ion conducting gel polymer electrolyte for lithium batteries

被引：49

作者：

Rohan, Rupesh ^{[1
]}

Sun, Yubao ^{[2
]}

Cai, Weiwei ^{[1
]}

Zhang, Yunfeng ^{[1
]}

Pareek, Kapil ^{[1
]}

Xu, Guodong ^{[1
]}

Cheng, Hansong ^{[1
,2
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore, Singapore

[2] China Univ Geosci, Sustainable Energy Lab, Wuhan 430074, Peoples R China

来源：

SOLID STATE IONICS | 2014年 / 268卷

基金：

新加坡国家研究基金会; 中国国家自然科学基金;

关键词：

Single ion electrolyte; Conductivity; Electrochemical stability; ELECTROCHEMICAL PROPERTIES; ORGANIC ELECTROLYTES; LIQUID ELECTROLYTES; SALTS; PERFORMANCE; MEMBRANES; BORATE;

D O I：

10.1016/j.ssi.2014.10.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lithium poly(4-styrene sulfonyl (phenylsulfonyl)imide) (PSSPSI) was synthesized through the Hinsberg reaction. Since the bis(sulfonyl)imide anion is immobilized in the polymer chain, the lithium cation transference number was measured to be 0.87. The weight average number molecular weight (M-w) was found to be 105,343 determined by gel permeation chromatography (GPC). A gel polymer electrolyte membrane, comprising of PVDF and PSSPSI, was successfully prepared with the ionic conductivity of 1.1 x 10(-3) S cm(-1) at room temperature. The membrane exhibits a wide electrochemical window up to 4.5 V (vs. Li+/Li) and is thermally and mechanically stable. The material is well suited for applications in lithium-ion batteries. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：294 / 299

页数：6

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