Remarkable stabilization of a ligand-based mixed-valence state in the metal-based mixed valent Ru2 II,III MII(μ3-O) (M = Co, Ni) trinuclear cluster complexes

被引：5

作者：

Tanaka, Maiko ^{[1
]}

Kariya, Nobuko ^{[1
]}

Abe, Masaaki ^{[1
]}

Sasaki, Yoichi ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Kita Ku, Sapporo, Hokkaido 0600810, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2007年 / 80卷 / 01期

关键词：

D O I：

10.1246/bcsj.80.192

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two consecutive one-electron reductions of the mixed-metal trinuclear complexes [Ru-III 2M(II)(mu(3)-O)(mu-CH3COO)(6)-(S)(bzpy)(2)] [(M = Co, S = H2O) and (M = Ni, S = N,N'-dimethylformamide); bzpy = 4-benzoylpyridine} in acetonitrile give stable "double" mixed-valence states where both Ru-2(II,III) and (bzpy(-))(bzpy) states coexist. Splitting of the ligand-based redox waves, (bzpy)(2)/(bzpy(-))(bzpy)/(bzpy(-))(2), is 0.35 and 0.34 V for the Co and Ni complexes, respectively.

引用

页码：192 / 194

页数：3

共 24 条

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Tanaka, Maiko
Kariya, Nobuko
Abe, Masaaki
Sasaki, Yoichi
Bulletin of the Chemical Society of Japan, 2007, 80 (01): : 192 - 194
[2] A new trinuclear mixed-valence Co(II)-Co(III) complex stabilized by a bis(salicylidene) based ligand
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POLYHEDRON, 2007, 26 (03) : 686 - 694
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INORGANICA CHIMICA ACTA, 2017, 454 : 107 - 116
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POLYHEDRON, 2009, 28 (9-10) : 1638 - 1645
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CHEMISTRY LETTERS, 2005, 34 (03) : 300 - 301
[10] ELECTRONIC INTERACTIONS IN MIXED-VALENCE AND MIXED-METAL ION CLUSTERS - INELASTIC NEUTRON-SCATTERING SPECTRA OF THE COMPLEXES [FE(III)2M(II)O(OOCME)6(PY)3](PY), WHERE M = MN, NI
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