Forbidden atomic oxygen emissions in the martian dayside upper atmosphere

Recently, Nadir and Occultation for Mars Discovery (NOMAD) ultraviolet and visible spectrometer instrument on board the European Space Agency's ExoMars Trace Gas Orbiter (TGO) simultaneously measured the limb emission intensities for both [OI] 2972 and 5577 angstrom (green) emissions in the dayside of Martian upper atmosphere. But the atomic oxygen red-doublet emission lines ([OI] 6300 and 6364 angstrom), which are expected to be observed along with [OI] 5577 and 2972 angstrom emissions, are found to be absent in the NOMAD-TGO dayside observed spectra. We aim to explore the photochemistry of all these forbidden atomic oxygen emissions ([OI] 2972, 5577, 6300, 6464 angstrom) in the Martian daylight upper atmosphere and suitable conditions for the simultaneous detection of these emissions lines in the dayside visible spectra. A photochemical model is developed to study the production and loss processes of O(S-1) and O(D-1), which are the respective excited states of green and red-doublet emissions, by incorporating various chemical reactions of different 0-bearing species in the upper atmosphere of Mars. By reducing Fox (2004) modelled neutral density profiles by a factor of 2, the calculated limb intensity profiles for [OI] 5577 and 2972 angstrom emissions are found to be consistent with the NOMAD-TGO observations. In this case, at altitudes below 120 km, our modelled limb intensity for [OI] 6300 angstrom emission is smaller by a factor 2 to 5 compared to that of NOMAD-TGO observation for [OI] 2972 angstrom emission, and above this distance it is comparable with the upper limit of the observation. We studied various parameters which can influence the limb intensities of these atomic oxygen forbidden emission lines. Our calculated limb intensity for [OI] 6300 angstrom emission, when the Mars is at near perihelion and for solar maximum condition, suggests that all these forbidden emissions should be observable in the NOMAD-TGO visible spectra taken on the dayside of Martian upper atmosphere. More simultaneous observations of forbidden atomic oxygen emission lines will help to understand the photochemical processes of oxygen-bearing species in the dayside Martian upper atmosphere.