Methoxycarbene and allenylidene complexes of ruthenium with an oxygen tripod ligand

被引：12
|
作者：
Leung, WH
Chan, EYY
Wong, WT
机构：
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong
[2] Univ Hong Kong, Hong Kong, Hong Kong
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 06期
关键词：
D O I：
10.1021/om970907e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Interaction of L-OEt(PPh3)(2)RuCl (L-OEt = (eta(5)- C5H5) Co[P(OEt)(2)=O)(3)] with Me3SiC=CH and 2-phenyl-3-butyn-2-ol in the presence of NH4PF6 in MeOH/THF afforded the structurally characterized methoxycarbene [L-OEt(PPh3)(2)Ru=C(OMe)Me]PF6 (1) and the allenylidene complex [L-OEt(PPh3)(2)Ru=C=C=CPhMe]PF6 (2), respectively. The Ru-C distances in 1 and 2 are 1.876(6) and 1.86(2) Angstrom, respectively. The cyclic voltammograms of 1 and 2 exhibit reversible Ru(III/II) couples at 0.58 and 0.64 V vs Cp2Fe+/0 respectively.
引用
收藏
页码：1245 / 1247
页数：3
相关论文
共 50 条
  • [1] Synthesis and electrochemistry of ruthenium complexes with an oxygen tripod ligand
    Leung, WH
    Chan, EYY
    Wong, WT
    INORGANIC CHEMISTRY, 1999, 38 (01) : 136 - 143
  • [2] Ruthenium thiocarbonyl and phosphoniodithiocarboxylate complexes with an oxygen tripod ligand
    Leung, WH
    Chan, EYY
    Lam, TCH
    Williams, ID
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 608 (1-2) : 139 - 145
  • [3] Organometallic compounds of ruthenium containing an anionic oxygen tripod ligand
    Leung, WH
    Chan, EYY
    Williams, ID
    Wong, WT
    ORGANOMETALLICS, 1997, 16 (14) : 3234 - 3240
  • [4] Organometallic compounds of ruthenium containing an anionic oxygen tripod ligand
    Organometallics, 14 (3234):
  • [5] ORGANOMETALLIC CUMULENES - ALLENYLIDENE AND ALKENYL ALLENYLIDENE RUTHENIUM COMPLEXES
    WOLINSKA, A
    TOUCHARD, D
    DIXNEUF, PH
    ROMERO, A
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 420 (02) : 217 - 226
  • [6] Nucleophilic Additions to Allenylidene Ruthenium Complexes
    Garcia de la Arada, Isaac
    Diez, Josefina
    Pilar Gamasa, M.
    Lastra, Elena
    ORGANOMETALLICS, 2015, 34 (07) : 1345 - 1353
  • [7] Pyrrolyl substituted allenylidene complexes of ruthenium
    Hartmann, S
    Winter, RF
    Sarkar, B
    Lissner, F
    DALTON TRANSACTIONS, 2004, (20) : 3273 - 3282
  • [8] Amphoteric allenylidene ruthenium complexes and the first dinuclear ruthenium species with a bis-alkenyl carbyne bridging ligand
    Rigaut, S
    Touchard, D
    Dixneuf, PH
    ORGANOMETALLICS, 2003, 22 (20) : 3980 - 3984
  • [9] Ruthenium-allenylidene complexes and their specific behaviour
    Rigaut, S
    Touchard, D
    Dixneuf, PH
    COORDINATION CHEMISTRY REVIEWS, 2004, 248 (15-16) : 1585 - 1601
  • [10] Reactivity of Ruthenium Allenylidene Complexes with Hydrazines: Formation of Acrylonitrile Complexes
    Cai, Tao
    Yang, Yu
    Zhang, Li
    Wen, Tingbin
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2018, 38 (08) : 2017 - 2027
12345