Self-assembly inclusion of green solvent with oligosaccharides

被引：13

作者：

Roy, Mahendra Nath ^{[1
]}

Roy, Kanak ^{[1
]}

Das, Koyeli ^{[1
]}

Barman, Biraj Kumar ^{[1
]}

机构：

[1] Univ N Bengal, Dept Chem, Darjeeling 734013, India

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2016年 / 216卷

关键词：

Green solvent; Oligosaccharides; Inclusion complex; Hydrophobicity; Formation constants; BETA-CYCLODEXTRIN; IONIC LIQUIDS; COMPLEXES; ALPHA; NANOTECHNOLOGY; CONDUCTANCE; SOLVATION;

D O I：

10.1016/j.molliq.2015.12.097

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work has been focused on the characteristics of green solvent i.e. 1-butyl-4-methylpyridinium iodide and some organic oligosaccharides, alpha- and beta-cyclodextrins in aqueous media. In aqueous solution, hydrophobic butyl side chain of the ionic liquid has been inserted into the hollow space of cyclodextrin. The selective formation of 1:1 inclusion complexes has been established here. Surface tension values, conductivity trends, and thermodynamic and spectroscopic study reveal that formations of inclusion complexes are more favorable and efficient for beta-CD than alpha-CD. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：132 / 136

页数：5

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