XAFS study on the photoinduced spin transition of [Fe(2-pic)3]Cl2•C2H5OH

被引：8

作者：

Okamoto, K ^{[1
]}

Nagai, K ^{[1
]}

Miyawaki, J ^{[1
]}

Kondoh, H ^{[1
]}

Ohta, T ^{[1
]}

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 371卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(03)00332-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A photoinduced spin transition state of [Fe-II(2-picorylamine)(3)]Cl-2 . C2H5OH was investigated by Fe K-edge X-ray-absorption fine structure (XAFS) spectroscopy. The X-ray-absorption near-edge structure (XANES) of the photoirradiated sample at 30 K is well reproduced as a superposition of those obtained at 298 and 30 K, corresponding to high- and low-spin phases, respectively. An analysis of the extended X-ray-absorption fine structure (EXAFS) shows that the Fe-N coordination in the photoinduced state is identical with that in the high-spin phase at room temperature, as confirmed by the bond distance and the Debye-Waller factor. (C) 2003 Published by Elsevier Science B.V.

引用

页码：707 / 712

页数：6

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