Synthesis and conformational properties of monoesters of calix[4]arene

被引:0
|
作者
Nam, KC [1 ]
Ko, SW [1 ]
Kim, JM [1 ]
机构
[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two synthetic procedures were developed for the preparation of monoesters of calix[4]arene, one via dibenzylation the other via monobenzylation route. Dibenzylation pathway can provide specifically mono-benzoester of calix[4]arene, but monobenzylation method could produce a series of monoesters of calix[4]arene such as acetyl, isobutyryl, and benzoesters. Conformational properties were discussed on the basis of H-1 and C-13 NMR data.
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页码:345 / 348
页数:4
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