Synthesis and properties of substituted [3-(2-hydroxyphenyl)-1H-1,2,4-triazol-1-yl]acetonitriles

被引：8
|
作者：
Shasheva, E. Yu. [1 ]
Vikrishchuk, N. I. [1 ]
Popov, L. D. [1 ]
Minkin, V. I. [1 ]
Kletskii, M. E. [1 ]
Antipin, M. Yu. [2 ]
Vikrishchuk, A. D. [3 ]
Mikhailov, I. E. [3 ]
机构：
[1] So Fed Univ, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, Nesmeyanov Inst Organometall Cpds, Moscow 119991, Russia
[3] Russian Acad Sci, So Res Ctr, Rostov Na Donu, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 46卷 / 07期
关键词：
Triazole; Colorless Crystal; Potassium Carbonate; Activate Methylene Group; Triazole Ring;
D O I：
10.1134/S1070428010070201
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkylation of 3-substituted 5-(2-hydroxyphenyl)-1H-1,2,4-triazoles with chloroacetonitrile gave hitherto unknown N-cyanomethyl derivatives whose structure was determined by X-ray analysis and (1)H and (13)C NMR spectroscopy. Condensation of substituted [3-(2-hydroxyphenyl)-1H-1,2,4-triazol-1-yl]acetonitriles at the activated methylene group with acetone led to the formation of new 3-methyl-2-triazolylbut-2-enenitrile derivatives.
引用
收藏
页码：1079 / 1084
页数：6
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