Novel synthesis of diethyl carbonate over palladium/MCM-41 catalysts

被引：20
|
作者：
Zhen, JX [1 ]
Hua, SY
Hua, CS
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310037, Peoples R China
[2] Acad Sinica, Inst Chem, Taipei, Taiwan
来源：
CATALYSIS LETTERS | 2000年 / 69卷 / 3-4期
关键词：
palladium supported MCM-41 catalysts; carbonylation; diethyl carbonate;
D O I：
10.1023/A:1019082209214
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic activities of palladium supported on Si-MCM-41 and Ti-MCM-41 catalysts have been studied in the reactions of CO + C2H5ONO. It reveals that copper and titanium used as additives are able to increase the yields of DEC and DEO. The additive copper is favorable to DEO formation, while the additive titanium is favorable to DEC formation.
引用
收藏
页码：153 / 156
页数：4
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