Characterization of residue from leached cathode ray tube funnel glass: reutilization as white carbon black

被引:7
|
作者
Yuan, Wenyi [1 ]
Yao, Zhitong [2 ]
Zhang, Qiwu [3 ]
Li, Jinhui [4 ]
机构
[1] Shanghai Polytech Univ 2, Shanghai Cooperat Ctr WEEE Recycling, Shanghai 201209, Peoples R China
[2] Hangzhou Dianzi Univ, Coll Mat Sci & Environm Engn, Hangzhou 310018, Zhejiang, Peoples R China
[3] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
[4] Tsinghua Univ, Sch Environm Sino Italian Environm & Energy Bldg, Beijing 100084, Peoples R China
基金
上海市自然科学基金;
关键词
CRT funnel glass; E-waste; Amorphous silica dioxide; White carbon black; Reutilization; LEAD RECOVERY; DISPOSAL;
D O I
10.1007/s10163-014-0291-5
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Cathode ray tube (CRT) funnel glass remains an urgent environmental problem and is composed mainly of lead oxide and silicon oxide. In this research, the residue could be obtained from 2 h to 500 rpm activated CRT funnel glass after extracting lead via acid leaching under the conditions of HNO3 concentration 1.0 mol/L, leaching temperature 95 A degrees C and leaching time 1 h. In order to reutilize the residue, its physico-chemical properties were characterized by scanning electron microscopy, Brunauer-Emmett-Teller, thermogravimetric analysis, X-ray diffraction and Fourier transform infrared spectroscopy. The results indicated that the residue was an amorphous superfine powder with approximately 93 wt% silica oxide and specific surface area of more than 170 m(2)/g. It can be reutilized as white carbon black.
引用
收藏
页码:629 / 634
页数:6
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