Competing Michael and Knoevenagel reactions of terpenoids with malononitrile on basic Cs-beta zeolite

被引：30

作者：

Volcho, KP

Kurbakova, SY

Korchagina, DV

Suslov, EV

Salakhutdinov, NF

Toktarev, AV

Echevskii, GV

Barkhash, VA

机构：

[1] Novosibirsk Organ Chem Inst, Novosibirsk 630090, Russia

[2] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2003年 / 195卷 / 1-2期

关键词：

basic zeolite; Michael reaction; Knoevenagel reaction; terpenoids; tandem reactions;

D O I：

10.1016/S1381-1169(02)00581-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Basic cesium-beta (Cs-beta) zeolite has been synthesized. It proved to be an effective catalyst in reactions of a number of alpha,beta-unsaturated carbonyl compounds with malononitrile. It is shown that the process is either the Michael or Knoevenagel reaction, or tandem transformations generally initiated by the Michael reaction, which depends on steric hindrance at the carboryl group and the beta-position of the carbon=carbon (C=C) double bond adjacent to the carbonyl group. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：263 / 274

页数：12

共 9 条

[1] Competing Michael and Knoevenagel reactions of terpenoids with malononitrile on basic cs-beta zeolite
Volcho, K.P.
Kurbakova, S.Yu.
Korchagina, D.V.
Suslov, E.V.
Salakhutdinov, N.F.
Toktarev, A.V.
Echevskii, G.V.
Barkhash, V.A.
[J]. J. Mol. Catal. A Chem., 1600, 1-2 (263-274):
[2] Cs-Beta with an Al-rich composition as a highly active base catalyst for Knoevenagel condensation
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Yokoi, Toshiyuki
[J]. APPLIED CATALYSIS A-GENERAL, 2019, 575 : 20 - 24
[3] Reactions of some terpenoids with CH-acids in the presence of Cs-β zeolite
Volcho, KP
Suslov, EV
Kurbakova, SY
Korchagina, DV
Salakhutdinov, NF
Barkhash, VA
[J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 40 (05) : 659 - 667
[4] Reactions of Some Terpenoids with CH-Acids in the Presence of Cs-β Zeolite
K. P. Volcho
E. V. Suslov
S. Yu. Kurbakova
D. V. Korchagina'
N. F. Salakhutdinov
V. A. Barkhash
[J]. Russian Journal of Organic Chemistry, 2004, 40 : 659 - 667
[5] INTERPHASE CATALYSIS IN MICHAEL AND KNOEVENAGEL REACTIONS WITH ALPHA,BETA-UNSATURATED ALDEHYDES
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[6] Synthesis of Oxynitrided Beta Zeolite and Its Applicationin Knoevenagel Reactions as Solid Base Catalysts
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[J]. Chinese Journal of Catalysis, 2001, (03) : 227 - 228
[7] Synthesis of oxynitrided beta zeolite and its application in Knoevenagel reactions as solid base catalysts
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[J]. CHINESE JOURNAL OF CATALYSIS, 2001, 22 (03) : 227 - 228
[8] Tandem Knoevenagel-Michael-cyclocondensation reactions of malononitrile, various aldehydes and dimedone using acetic acid functionalized ionic liquid
Moosavi-Zare, Ahmad Reza
Zolfigol, Mohammad Ali
Khaledian, Omid
Khakyzadeh, Vahid
Farahani, Majid Darestani
Kruger, Hendrik Gerhardus
[J]. NEW JOURNAL OF CHEMISTRY, 2014, 38 (06) : 2342 - 2347
[9] Fe3O4-Methylene diphenyl diisocyanate-guanidine (Fe3O4-4,4-MDI-Gn): A novel superparamagnetic powerful basic and recyclable nanocatalyst as an efficient heterogeneous catalyst for the Knoevenagel condensation and tandem Knoevenagel-Michael-cyclocondensation reactions
Maleki, Razieh
Koukabi, Nadiya
Kolvari, Eskandar
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (01)

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