Chemical oxidation of fluoroanilines to fluoroazobenzenes and fluorophenazines with potassium ferricyanide and potassium hydroxide

被引：13

作者：

Leyva, E ^{[1
]}

Medina, C ^{[1
]}

Moctezuma, E ^{[1
]}

Leyva, S ^{[1
]}

机构：

[1] Univ Autonoma San Luis Potosi, Fac Ciencias Quim, San Luis Potosi 78210, Mexico

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2004年 / 82卷 / 12期

关键词：

oxidation; fluoroanilines; fluoroazobenzenes; fluorophenazines;

D O I：

10.1139/V04-150

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of several fluoroanilines with potassium ferricyanide and potassium hydroxide is described. In this oxidation, the major products are fluoroazobenzenes. In the case of 2-fluoro-substituted anilines, heterocyclic fluorophenazines were obtained in low to moderate yields. The optimal conditions for the reaction and the mechanism are presented.

引用

页码：1712 / 1715

页数：4

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