Functionalized Silver Nanoparticle Catalyzed [3+2] Cycloaddition Reaction: Greener Route to Substituted-1,2,3-triazolines

被引：4

作者：

Hemmaragala, Nanjundaswamy Marishetty ^{[1
]}

Abrahamse, Heidi ^{[1
]}

George, Blassan Plackal Adimuriyil ^{[1
]}

Gannimani, Ramesh ^{[2
]}

Govender, Patrick ^{[2
]}

机构：

[1] Univ Johannesburg, Laser Res Ctr, Fac Hlth Sci, POB 17011, ZA-2028 Doornfontein, South Africa

[2] Univ KwaZulu Natal, Sch Life Sci, ZA-4000 Durban, South Africa

来源：

CATALYSIS LETTERS | 2016年 / 146卷 / 02期

关键词：

Functionalized silver nanoparticles; Protorhuslongifolia; Catalysis; 3+2]cycloaddition; 1,5-Disubstituted-1,2,3-triazolines; ANTIBACTERIAL ACTIVITY; PROTORHUS-LONGIFOLIA; ANTICANCER ACTIVITY; SEED EXTRACT; PEEL EXTRACT; 1,2,3-TRIAZOLES;

D O I：

10.1007/s10562-015-1653-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The [3+2] cycloaddition reaction between nitroolefins and alkyl/aryl azides was studied using functionalized silver nanoparticles (FnAgNPs) of average diameter 23 +/- A 1 nm as catalyst produced by the plant extract Protorhus longifolia. We found FnAgNPs to catalyze the reactions efficiently yielding a series of 1,5-disubstituted-1,2,3-triazolines under mild reaction conditions with no side products. The catalytic activity of FnAgNPs was compared with naked AgNPs and FnAgNPs found to be very effective. Except solvents, the whole experiments do not require any chemical/reagent which makes the process green. [GRAPHICS]

引用

页码：464 / 473

页数：10

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