Synthesis of Silica-Supported Platinum(II) and Nickel(II) Complexes of Bis(Diphenylphosphinomethyl)Amino Ligand: Applications as Catalysts for the Synthesis of 2-Methyl-1,4-Naphthoquinone (Vitamin K3)

被引：14

作者：

Urus, Serhan ^{[1
]}

Keles, Mustafa ^{[2
]}

Serindag, Osman ^{[3
]}

机构：

[1] Sutcu Imam Univ, Univ Ind Publ, Res Dev & Applicat Ctr, TR-46100 Kahramanmaras, Turkey

[2] Osmaniye Korkut Ata Univ, Dept Chem, Fac Sci & Letters, TR-80000 Osmaniye, Turkey

[3] Cukurova Univ, Fac Sci & Letters, TR-01330 Adana, Turkey

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2010年 / 20卷 / 01期

关键词：

Vitamin K-3; Menadione; Phosphines; Naphthoquinones; Oxidation; Silica-supported catalyst; BAEYER-VILLIGER OXIDATION; PALLADIUM COMPLEXES; HYDROGEN-PEROXIDE; CRYSTAL-STRUCTURE; PHOSPHINES; ARENES;

D O I：

10.1007/s10904-010-9328-y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Pt(II) and Ni(II) complexes of N,N-bis(diphenylphosphinomethyl)aminopropyltriethoxysilane [(CH3CH2O)(3)Si(CH2)(3)N(CH2PPh2)(2)] (DIPAPTES) and silica supported [SiO2-(DIPAPES)] ligands have been synthesized under nitrogen atmosphere using Schlenk method and characterized by using atomic absorption, FT-IR, NMR (H-1 and P-31) and elemental analysis techniques. All the complexes were used as catalysts for the oxidation of 2-methyl naphthalene (2MN) to 2-methyl-1,4-naphthoquinone (vitamin K-3, menadione, 2MNQ) using hydrogen peroxide as a clean and cheap oxidant. [Pt-(DIPAPTES)Cl-2] and supported complex [SiO2-(DIPAPES)-PtCl2] showed medium catalytic activity whereas Ni(II) complexes did not show any catalytic activity for the selective oxidation of 2-methyl naphthalene to 2-methyl-1,4-naphthoquinone.

引用

页码：152 / 160

页数：9

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