Effect of removal organic sulfur from coal macromolecular on the properties of high organic sulfur coal

被引：36
|
作者：
Tang, Longfei [1 ,2 ]
Chen, Songjiang [1 ,2 ]
Gui, Dongjiao [1 ,2 ]
Zhu, Xiangnan [3 ]
He, Huan [1 ,2 ]
Tao, Xiuxiang [1 ,2 ]
机构：
[1] China Univ Min & Technol, Key Lab Coal Proc & Efficient Utilizat, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China
[2] China Univ Min & Technol, Sch Chem Engn & Technol, Xuzhou 221116, Jiangsu, Peoples R China
[3] Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Shandong, Peoples R China
来源：
FUEL | 2020年 / 259卷
关键词：
Coal properties; Reductive desulfurization; High organic sulfur; Coal macromolecular; PEROXYACETIC ACID; MICROWAVE IRRADIATION; SUBBITUMINOUS COAL; DE-SULFURIZATION; ACTION MECHANISM; DESULFURIZATION; REDUCTION; OXIDATION; EXPLORATION; WATER;
D O I：
10.1016/j.fuel.2019.116264
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The present work investigated the effect of efficient reduction desulfurization method (potassium tertbutoxide and hydrosilane system) on coal properties. Characteristic changes of high organic sulfur coal were studied utilizing TGA, FTIR and XPS after desulfurization. Results showed that more than 60% organic sulfur was removed, while the calorific value of coal samples decreased slightly and the aromatics in coal macromolecular structure were destroyed little. After treatment, formation of low molecular fragments from aliphatic carbons leaded to the increase of mass loss in TGA. XPS results revealed that some oxygen-containing groups were deoxidized after reduction treatment. The changes of coal properties were mainly attributed to the fracture of branch chain, the reduction of oxidized carbon atoms and side reactions during reduction desulfurization.
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页数：8
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