A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

被引：43
|
作者：
Oyman, ZO
Ming, W
Micciché, F
Oostveen, E
van Haveren, J
van der Linde, R
机构：
[1] Eindhoven Univ Technol, Lab Coatings Technol Mat & Interface Chem, NL-5600 MB Eindhoven, Netherlands
[2] ATO BV, Dept Polymers Composites & Addit, NL-6700 AA Wageningen, Netherlands
来源：
POLYMER | 2004年 / 45卷 / 22期
关键词：
polymer chemistry; polymer materials;
D O I：
10.1016/j.polymer.2004.08.052
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7-triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7431 / 7436
页数：6
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